If the directive from the state is to cast (or shotcrete) both the slab and the walls monolithically, this would be a difficult task with either shotcrete or cast concrete. If the directive is to cast the floor monolithically, and then the walls monolithically, shotcrete could certainly be used and would be considered a monolithic placement. Once the state’s intent is clarified, this question should be posed to a shotcrete contractor who might be the actual contractor on the project for their input.
As this is a fertilizer plant, there may be additional considerations due to the potentially aggressive nature of the fluids introduced into this pit.